Acousto-Electronic Sensor Based on Langmuir-Blodgett Films of Tetra-Tert-Butylphthalocyaninate Zinc for Chemical Vapor Detection.

In this work, the sensor properties of multilayered Langmuir-Blodgett (LB) films of tetra-tert-butylphthalocyaninate zinc (tBuZnPc) were studied using an acoustoelectronic method. The morphology and optical properties of the fabricated films were characterized by atomic force microscopy and ultraviolet-visible spectroscopy, respectively. The LB films were deposited on surface acoustic wave (SAW) delay lines, and their gas-sensing properties were investigated. The films demonstrated high selectivity towards chloroform vapor compared to acetone, methanol, ethanol, and isopropanol. The highest selectivity was observed for the five-layer film, which can be attributed to the specific interaction of chloroform molecules with the hydrophobic cavities formed by the tert-butyl groups. Increasing the film thickness to 41 layers enhanced the absolute response to chloroform to 370 ppm; however, the selectivity decreased due to increased nonspecific adsorption. The results demonstrate the potential of using tBuZnPc LB films as sensitive coatings for the selective detection of chloroform in environmental and industrial monitoring applications.