Towards Portable One-Drop Voltammetry with Doped Screen-Printed Electrodes to Control Preservatives: A New Tool for Diuron and Isoproturon in the Paint Industry.

The use of preservatives such as diuron and isoproturon in the paint industry is essential to protect products against microbial attack. However, these compounds are subject to strict regulation due to the harmful effects they have on the environment and human health. Therefore, analytical strategies to control the production process at paint plants are fundamental to ensure suitable products. In the present work, a low-cost portable square-wave voltammetry device with commercial screen-printed electrodes was proposed to control the starting products and to determine isoproturon and diuron levels in manufactured paint products. Under the optimized conditions (electrolyte HClO4 0.18 M, nickel oxide-doped carbon electrodes, ESW = 0.02 V, Estep = 0.0015 V, and ƒ = 15 Hz), the results indicated satisfactory analytical performance, with detection limits of 3.5 and 3.0 mg L-1 for isoproturon and diuron, respectively, and precision lower than 7.5% for both biocides. The analytical strategy employed to achieve satisfactory selectivity involved taking advantage of the specific interaction of cysteine with 1,2-benzisothiazol-3(2H)-one (BIT) as a potential interferent in some commercial products and the use of matrix match calibration. A recovery study provided values in the range of 92-104% for accuracy validation. A sample pretreatment step was needed due to the paint composition, and a miniaturized method was proposed here. The novelty of this method lies in the use of a portable voltammetry device in real-world industrial applications to control the paint production process using a cost-effective, time-saving, sustainable, and green protocol. The HEXAGON tool is used for assessing greenness and sustainability. The choice of reagents like HClO4 and the minimization of waste from the small volumes used align with the principles of using safer solvents, a key concern in green and sustainable chemistry.