Towards Fire-Safe Polymer Electrolytes for Lithium-Ion Batteries: Strategies for Electrolyte Design and Structural Design.

Lithium-ion batteries, widely used in phones and electric vehicles, pose safety concerns due to the flammability of conventional liquid electrolytes, which are prone to ignition under elevated temperatures and mechanical stress, increasing the risk of fire. Polymer electrolytes have been employed as a safer solution thanks to their superior thermal stability and mechanical strength. However, despite these advantages, many polymer matrices pose a fire hazard, limiting their potential. This review assesses recent advances in enhancing the flame retardancy of polymer electrolytes through a variety of strategies, namely the incorporation of flame-retardant additives, the addition of nanoscale fillers to improve thermal resistance, and the design of layered or hybrid polymer membrane structures that function as thermal barriers. This review evaluates the effectiveness of these methods, examining their flame-retardancy as well as their influences on ionic conductivity and overall battery performance. By highlighting recent progress and enduring safety challenges in solid-state batteries, it aims to offer insights for developing lithium batteries with enhanced safety and high performance.