Low-Cost Biomass Nanofibers from Chitosan and Phytic Acid for Efficient Uranium Extraction.

Exploring materials for the uranium extraction from seawater holds great significance for the sustainable development of the nuclear industry. Though many adsorbents have been investigated to extract uranium, they still suffer from the issues of low adsorption performance and high production cost. In this work, biomass nanofiber adsorbents (PA-CS NFs) were prepared by the electrospinning of chitosan followed by functionalization with phytic acid. Based on the cost analysis, the preparation expense of PA-CS NFs was $16.4 kg-1, lower than those of common synthetic polymer adsorbents. In addition, PA-CS NFs showed fast removal kinetics (equilibrium time = 60 min), high uptake capacity (457.8 mg g-1), and good selectivity (the ratio of uranium/competing ion capacities > 3.8) from uranium spiked solution. PA-CS NFs also exhibited the ability to remove trace uranyl ions (distribution coefficient = 4.7 × 105 mL g-1) and satisfy recycling capacity. The experimental tests and theoretical calculations confirmed that the phosphate groups in the functionalized phytic acid displayed the main contribution to the uranyl ion adsorption, which had higher binding energy than the functional groups in chitosan. Benefiting from the good adsorption ability, low cost, and macroscopical membrane form, PA-CS NFs were applied to natural seawater for uranium extraction, and an extraction capacity of 4.52 mg g-1 could be achieved after 35 days' testing. On account of the obtained results, this study offers an efficient and low-cost nanofiber adsorbent for uranium extraction.