Strength in Adhesion: A Multi-Mechanics Review Covering Tensile, Shear, Fracture, Fatigue, Creep, and Impact Behavior of Polymer Bonding in Composites.

The growing demand for lightweight and reliable structures across aerospace, automotive, marine, and civil engineering has driven significant advances in polymer adhesive technology. These materials serve dual roles, functioning as matrices in composites and as structural bonding agents, where they must balance strength, toughness, durability, and sometimes sustainability. Recent review efforts have greatly enriched understanding, yet most approach the topic from specialized angles-whether emphasizing nanoscale toughening, multifunctional formulations, sustainable alternatives, or microscopic failure processes in bonded joints. While such perspectives provide valuable insights, they often remain fragmented, leaving open questions about how nanoscale mechanisms translate into macroscopic reliability, how durability evolves under realistic service conditions, and how mechanical responses interact across different loading modes. To address this, the present review consolidates knowledge on the performance of polymer adhesives under tension, shear, fracture, fatigue, creep, and impact. By integrating experimental findings with computational modeling and emerging data-driven approaches, it situates localized mechanisms within a broader structure-performance framework. This unified perspective not only highlights persistent gaps-such as predictive modeling of complex failure, scalability of nanomodified systems, and long-term durability under coupled environments-but also outlines strategies for developing next-generation adhesives capable of delivering reliable, high-performance bonding solutions for demanding applications.