Pseudocapacitive Behavior of Blade-Coated Mo1.33CTx i-MXene Electrodes in Aqueous Electrolytes.

Two-dimensional molybdenum carbide (Mo1.33CTx MXene) with ordered vacancies is one of the most promising materials for electrochemical energy storage. However, the high defectivity and tendency to aggregate of nanosheets hinders the large-scale fabrication of highly efficient Mo1.33CTx -based electrodes. In this study, Mo1.33CTx/carbon nanotubes (CNTs) electrodes of varying thicknesses were fabricated using a scalable doctor blade technique. Their electrochemical performance was studied in H2SO4, H3PO4, LiCl and KCl electrolytes using cyclic voltammetry and galvanostatic charge-discharge methods. Electrodes with an active material mass loading of 1.6 mg/cm2 exhibited specific capacitances of 352, 287, 172, and 107 F/g in H2SO4, H3PO4, LiCl, and KCl electrolytes, respectively, at a scan rate of 2 mV/s. Increasing the mass loading of the electrode material to 3.5 mg/cm2 resulted in a specific capacitance of 349, 260, 162 and 98 F/g in the same electrolytes. The incorporation of CNTs enabled rapid electrolyte ion transport throughout the electrode bulk, maintaining high capacitance values even at high scan rates. These results open new avenues for the development of high-performance electrode materials for supercapacitors.