Facile Synthesis of Mg-MOF-74 Thin Films for Enhanced CO2 Detection.

Metal-organic frameworks (MOFs) are a class of highly ordered nanoporous crystals that possess a designable framework and unique chemical versatility. MOF thin films are ideal for nanotechnology-enabling applications, such as optoelectronics, catalytic coatings, and sensing. Mg-MOF-74 has been drawing increasing attention due to its remarkable CO2 uptake capacity among MOFs and other commonly used CO2 absorbents. Mg-MOF-74 thin films are currently fabricated by immersing selected substrates in precursor solutions, followed by a traditional solvothermal synthesis process. Herein, we introduce a rapid, easy, and cost-effective synthesis protocol to fabricate MOF thin films in an additive manner. In this work, the controllable synthesis of Mg-MOF-74 thin films directly on optical supports is reported for the first time. Dense, continuous, and uniform Mg-MOF-74 thin films are successfully fabricated on bare glass slides, with an average growth rate of up to 85.3 nm min-1. The structural and optical properties of the resulting Mg-MOF-74 thin films are characterized using X-ray diffraction, atomic force microscopy, scanning electron microscopy, UV-Vis-NIR spectroscopy, and Fourier Transform Infrared Spectroscopy (FTIR). The CO2 adsorption performance of the resulting Mg-MOF-74 thin films is studied using FTIR for the first time, which demonstrates that, as per the length of the light path for gas absorption, 1 nm Mg-MOF-74 thin film could provide 400.9 ± 18.0 nm absorption length for CO2, which is achieved via the extraordinary CO2 adsorption by Mg-MOF-74. The synthesis protocol enables the rapid synthesis of MOF thin films, highlighting Mg-MOF-74 in more CO2-related applications, such as enhanced CO2 adsorption and MOF-enhanced infrared gas sensing.