Catalytic Reductive Fractionation of Castor Shells into Catechols via Tandem Metal Triflate and Pd/C Catalysis.

In this work, the one-pot catalytic reductive fractionation of C-lignin in castor shell powders to efficiently provide catechyl monomers was achieved by tandem metal triflate and Pd/C catalysis. The optimized Pd/C + In(OTf)3 combination performed best and provided a 66.9 mg·g-1 yield of corresponding aromatic monomers with the catechol selectivity as high as 95.4%. For the promotion effect of the Lewis acid species, the mechanism studied indicated that the introduction of In3+ could significantly promote the C-O bond cleavage in the LCC to release the C-lignin fragments from the solid lignocellulose and simultaneously accelerate the cleavage of the critical Cα/β-OAr linkage bond in C-lignin to release catechol monomers. In addition, performance differences highlight the cooperation and function-matching effect between the hydrogenation metals and the Lewis ion species, which can promote the high-value utilization of forestry and agricultural residues in chemical synthesis.