A Comprehensive Review on Hydrogen Production from Biomass Gasification.

Hydrogen production from biomass gasification has emerged as a strategic pathway for achieving carbon-neutral energy systems, circular resource utilization, and sustainable fuel generation. As global energy systems transition toward renewable sources, biomass-derived hydrogen represents a cornerstone of waste valorization, negative-emission bioenergy, and green hydrogen economies. Among all technologies, hydrogen production through gasification is one of the most consolidated routes with plenty of operative industrial-scale plants. The field of gasification is quite complex, and this comprehensive review describes the current scientific and technological achievements of biomass gasification for hydrogen production, describing the effect of feedstock, reactivity phenomena, reactor design, and catalyst systems. Furthermore, we report on a quantitative analysis regarding the operative cost of gasification of biomass compared with green hydrogen production and methane reforming. We provide a complete and synthetic picture for one of the most critical fields in the hydrogen economy that can actively promote a transition towards a more sustainable society.