Electrochemical Performance of Dysprosium-Doped Strontium Cobaltite with Perovskite Structure.

The electrochemical properties of the dysprosium-doped strontium cobaltite SDC (Sr0.8Dy0.2CoO3-δ) were evaluated for possible application as pseudocapacitor electrode materials. Dense perovskite SDC ceramics were prepared using standard solid-state synthesis techniques. The SDC sample was characterized using XRD, structural analysis, SEM/EDS, and simultaneous thermal analysis. The electrochemical performance of the electrode was estimated in 3M KOH in a standard electrochemical cell for corrosion studies using cyclic voltammetry, impedance spectra, galvanostatic charge/discharge, and long-term cycling stability. The study demonstrated that the SDC exhibits high oxygen mobility and has the ability to release or incorporate oxygen from the gas phase. This process leads to the formation of structural anion vacancies without compromising the structural integrity. The SDC electrode demonstrates a specific capacitance of approximately 500 F/m2 and exhibits satisfactory cyclability. Electrochemical treatment in charge-discharge cycles has been shown to result in the formation of a thin strontium-depleted layer on the electrode surface. The observed behavior is believed to be caused by a high concentration of oxygen vacancies, which is consistent with oxygen intercalation into the perovskite structure. The present study suggests that rare earth-doped strontium cobaltite may serve as a prospective precursor for electrode material in supercapacitors.