Geopolymer Foams Loaded with Diatomite/Paraffin Granules for Enhanced Thermal Energy Storage.

This paper presents the development and characteristics of geopolymer foams modified with paraffin-based phase change materials (PCMs) encapsulated in diatomite. The aim was to increase both the thermal insulation and heat storage capacity of the foams while maintaining sufficient mechanical strength for construction applications. Eleven variants of composites with different PCM fractions (5-10% by mass) and grain sizes (<1.6 mm to >2.5 mm) were synthesized and tested. The inclusion of PCM encapsulated in diatomite modified the porous structure: the total porosity increased from 6.6% in the reference sample to 19.6% for the 1.6-1.8 mm_10% wt. variant, with pore diameters ranging from ~4 to 280 µm. Thermal conductivity (λ) ranged between 0.090-0.129 W/m·K, with the lowest values observed for composites 2.0-2.5 mm_5-10% wt. (≈0.090-0.091 W/m·K), which also showed high thermal resistance (R ≈ 0.287-0.289 m2·K/W). The specific heat (Cp) increased from 1.28 kJ/kg·K (reference value) to a maximum value of 1.87 kJ/kg·K for the 2.0-2.5 mm_10% mass variant, confirming the effective energy storage capacity of PCM-modified foams. Mechanical tests showed compressive strength values in the range of 0.7-3.1 MPa. The best structural performance was obtained for the 1.6-1.8 mm_10% wt. variant (3.1 MPa), albeit with a higher λ (≈0.129 W/m·K), illustrating the classic trade-off between porosity-based insulation and mechanical strength. SEM microstructural analysis and mercury porosimetry confirmed the presence of mesopores, which determine both thermal and mechanical properties. The results show that medium-sized PCM fractions (1.6-2.0 mm) with moderate content (≈10% by weight) offer the most favorable compromise between insulation and strength, while thicker fractions (2.0-2.5 mm) maximize thermal energy storage capacity. These findings confirm the possibility of incorporating natural PCMs into geopolymer foams to create multifunctional materials for sustainable and energy-efficient building applications. A unique contribution to this work is the use of diatomite as a natural PCM carrier, ensuring stability, compatibility, and environmental friendliness compared to conventional encapsulation methods.