The Journal of chemical physics
Realization of heptagonal pyramidal octacoordination in highly robust [OB-M©B7O7]- (M = Co, Rh, Ir) complexes via boron-oxygen synergy.
Bo Jin, Zai-Ran Wang, Yan-Bo Wu
Published: 202510.1063/5.0299288
Abstract
Non-spherical heptagonal pyramidal octacoordination has remained elusive due to extreme repulsion among equatorial ligands. Herein, we computationally demonstrate this unprecedented configuration in monoanionic [OB-M©B7O7]- (M = Co, Rh, Ir) complexes…
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