Interfacial effects and topological architecture synergistically govern three-dimensional self-assembly morphology of polyethylene-based block copolymers.

While block copolymers (BCPs) readily achieve 1D/2D architectures through crystallization-driven self-assembly (CDSA) in solution, assembling of 3D nanostructures faces thermodynamic and kinetic constraints. To address this, we optimized thermodynami…

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