Photoredox catalyzed synthesis of β-trifluoromethyl β-aminoketones from N-trifluoroethyl hydroxylamine reagent and silyl enol ethers.

This study presents a photoredox-catalyzed two-component alkylative coupling between silyl enol ethers and an N-trifluoroethyl hydroxylamine reagent via a radical 1,2-H shift, establishing a novel synthetic route toward β-trifluoromethyl β-aminoketon…

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