Dalton transactions (Cambridge, England : 2003)
Design of boron-decorated bimetallic iron complexes related to the active site of [FeFe]-hydrogenases and reactivity with hydride donors.
Ines Bennour, Victor Monnot, Philippe Schollhammer, Lucile Chatelain
Published: 202610.1039/d5dt02885j
Abstract
The reactivity of the 1,2-dithiolene diiron complexes [Fe2(µ-SCHC(Ph)S)(PR3)n(CO)6-n] (n = 0, or n = 1, R = Me or n = 1, 2, R = Ph) with the reagent HB(C6F5)2 is described. With the hexacarbonyl precursor, the reaction gives an anti-Markovnikov addi…
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