Crystallographic evidence of a trinuclear (salen)manganese(IV/III/IV)-μ-oxo formed during catalytic C(sp3)-H oxidation reactions.

The formation of manganese-oxo catalysts involved in C(sp3)-H bond oxidation was explored in the targeted synthesis of (salen/salophen)manganese complexes that varied axial ligand identity and varied oxidation state of the manganese center. Isolated…

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