Dalton transactions (Cambridge, England : 2003)
Gold(I) alkoxide and thiolate complexes as potential atomic layer deposition precursors.
Nicholas A Hoffman, David J H Emslie
Published: 202610.1039/d5dt02836a
Abstract
Reactions of AuCl(PR3) with NaOC(CF3)3 in the presence of 1 equiv. of Ag[BF4] or Ag[PF6] afforded the gold(I) alkoxide complexes [(Au{OC(CF3)3}{PR3})n] (R = Me (1), Et (2), iPr (3) and tBu (4)). In our hands, analogous reactions using NaOtBu (for R =…
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