Dalton transactions (Cambridge, England : 2003)
Hydroboration of carbonyl compounds catalysed by a molybdenum germylyne complex: metal-ligand cooperative mechanism.
Christof Fontanilla, Yuto Shimizu, Koichi Nagata, Sakura Iwatsuki, Aoi Tanamura, Seiji Mori, Tara Prasad Dhungana, Hisako Hashimoto
Published: 202610.1039/d5dt02829a
Abstract
A molybdenum germylyne complex with a MoGe triple bond promotes the catalytic hydroboration of aldehydes and ketones with HBpin. Hydroboration of aldehydes proceeded efficiently at ambient temperature, affording the corresponding borate esters in 92…
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