Dalton transactions (Cambridge, England : 2003)
Unprecedented 1,2-mesityl shift for the synthesis of iridafurans.
Maria Talavera, Antonio Gómez, Nicolás Otero, Ángeles Peña-Gallego, Sandra Bolaño
Published: 202610.1039/d5dt02755a
Abstract
The reactivity of tertiary propargylic alcohols bearing a mesityl substituent with [IrCp*Cl(NCMe)(PMe3)]PF6 has revealed a previously unreported 1,2-mesityl rearrangement, leading to the formation of α-iridafuran complexes. Comparative analysis with…
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