Dalton transactions (Cambridge, England : 2003)
Single-crystal to single-crystal synthesis of a gold(I)-ammonia complex and H/D exchange in crystallo with D2O.
Chloe L Johnson, Kristof M Altus, Miquel Navarro, Jesús Campos, Simon B Duckett, Andrew S Weller
Published: 202510.1039/d5dt02464a
Abstract
Single-crystal to single-crystal solid/gas reactivity of [LAu(C2H4/CO)][BArF4] [L = tris-2-(4,4'-di-tert-butylbiphenyl)phosphine] with NH3 or 15NH3 gives the ammonia complexes [LAu(NH3/15NH3)][BArF4]. Solid-gas H/D exchange with D2O vapour gives the…
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