Dalton transactions (Cambridge, England : 2003)
Electronic effects of substituents on the catalytic conversion of thiolates to alcohols by carboxylate bridged nonheme binuclear Fe(II) and Co(II) complexes.
Anuj Baran Chakraborty, Rajib Hazra, Srimayee Mukherjee, Amit Majumdar
Published: 202610.1039/d5dt02420j
Abstract
A detailed study for the catalytic hydrolysis of 10 thiolates and thiobenzoate at RT to alcohols/phenols and benzoic acid, respectively, by three new dicobalt(II) complexes, [Co2(PhBIMP)(µ-O2C-C6H3-2,6-(R1)2)(X)]2+ (R1 = -OMe, X = DMF, 2d; R1 = -F, X…
Preview only. Read the full abstract at the source