Dual deoxygenation in an α-ketoimine chelated rhenium(III) complex: structural and mechanistic interpretations.

An unprecedented case of dual deoxygenation is demonstrated in rhenium chemistry. It is authenticated that an oxorhenium(V) motif and a chelated diaryl-α-ketooxime ligand undergo concurrent oxygen atom transfer (OAT) to form a triarylphosphine oxide…

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