Dalton transactions (Cambridge, England : 2003)
Heterolytic cleavage of the B-H bond in H3B·L (L = THF, NMe2H) by an electrophilic Ir(III) pincer complex [Ir(H)(PMe3)(tBu4POCOP)][BArF4].
Mitarani Pradhan, Zeel Y Surati, Apurba Kumar Pal, Kumar Vanka, Balaji R Jagirdar
Published: 202610.1039/d5dt01780g
Abstract
Six- and five-coordinate iridium complexes, [Ir(H)Cl(PMe3)(tBu4POCOP)] (2) (tBu4POCOP = κ3-C6H3-2,6-(OPtBu2)2) and [Ir(H)(PMe3)(tBu4POCOP)][BArF4] (3), respectively, have been synthesized and characterized. The reactivity of the electrophilic 16-elec…
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