Physical chemistry chemical physics : PCCP
Compensation relationship in thermodynamics of gas-phase molecular complexation.
Andrey A Sokolov, Mansur B Khisamiev, Boris N Solomonov, Mikhail I Yagofarov
Published: 202510.1039/d5cp04241k
Abstract
The compensation relationship in thermodynamics is a linear correlation between enthalpy (ΔH) and entropy (ΔS) changes in a series of related systems. For the past 90 years of research, its manifestations in numerous processes were observed (also in…
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