Chemical communications (Cambridge, England)
Stepwise coordination of {Cu(C5Me5)} with a tri-silylated Ge9 cluster.
Tianzi Chen, Xinyue Wang, Yulin Han, Chenxi Guo, Dongyu Duan, Yu Tang, Fuxing Pan
Published: 202610.1039/d5cc06017f
Abstract
A stepwise reaction between [Ge9Hyp3]- and CuI/K(C5Me5) yielded the {Ge9Hyp3} hybridized double-decker sandwich cluster [{Cu(C5Me5)}2(η3:η3-Ge9Hyp3)]- (2) via [Cu(C5Me5)(η3-Ge9Hyp3)]- (1) as an intermediate. The controllable coordination of {Cu(C5Me5…
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