Chemical communications (Cambridge, England)
High-nuclearity Cu14 ionic complex featuring 1,3-bis(diphenylphosphino)propane and methylsilsesquioxane ligands: highly efficient catalysis of mild peroxidative alkane fuctionalizations.
Ivan S Arteev, Victor N Khrustalev, Lidia S Shul'pina, Alexey N Rodionov, Elena S Shubina, Karim Ragimov, Zhi Wang, Alexey N Bilyachenko
Published: 202610.1039/d5cc05805h
Abstract
The first metallacomplex containing both 1,3-bis(diphenylphosphino)propane and silsesquoxane ligands is presented, which adopts an intriguing three-component ionic structure. According to X-ray diffraction studies, the central dianionic CuII12-methyl…
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