Chemical communications (Cambridge, England)
Chain-length-dependent reactivity of alkenyl phosphates in ruthenium-catalyzed cross-metathesis.
Apicha Pontavatchai, Kevin Schwedtmann, Philipp Royla, Kai Schwedtmann, Tossapol Khamnaen, Uwe Schwarzenbolz, Thomas Henle, Ekasith Somsook, Jan J Weigand
Published: 202610.1039/d5cc05790f
Abstract
We report a chain-length-dependent reactivity pattern in the cross-metathesis of alkenyl phosphates catalyzed by the second-generation Grubbs catalyst (GII). While vinyl phosphates undergo unproductive decomposition to generate a ruthenium-carbide co…
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