Chemical communications (Cambridge, England)
Selective strain-promoted reactivity of a fluorene-derived [6]cycloparaphenyleneacetylene carbon nanohoop.
Robert J Herman, Said Jalife, Abigail G LeBlanc, Muhammad Usama Gul Khan, Marvin L Stewart, Sheila W Njoroge, Sajila Riman Tanha, Frank R Fronczek, Judy Wu, Semin Lee
Published: 202610.1039/d5cc05493a
Abstract
The modular synthesis of a fluorene-based nanohoop containing six strained alkynes is described herein. We demonstrate its scalability using alkyne metathesis as the macrocyclization method and its reactivity with azides using strain-promoted azide-a…
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