Chemical communications (Cambridge, England)
Asymmetric kinetic resolution polymerization of racemic O-carboxyanhydride catalyzed by cinchona alkaloids.
Yanju Jia, Rulin Yang, Hongguang Sun, Xuanhua Guo, Guangqiang Xu, Qinggang Wang
Published: 202510.1039/d5cc05378a
Abstract
The enantioselective ring-opening polymerization of O-carboxyanhydride (OCA) has been demonstrated for the first time. Utilizing a cinchona alkaloid derivative featuring a confined chiral pocket, the asymmetric kinetic resolution polymerization (AKRP…
Preview only. Read the full abstract at the source