Chemical communications (Cambridge, England)
Photocyclisations of o-iodobenzyl-indanones and tetralones infer the intermediacy of triplet aryl cations.
Marian E Powderly, Toby Lindup, Edward H Jackman, Mark E Light, Julien Legros, Isabelle Chataigner, David C Harrowven
Published: 202510.1039/d5cc05185a
Abstract
Photocyclisations of aryl iodides to 2-indanones and 2-tetralones give different outcomes to analogous radical reactions implicating the intermediacy of triplet aryl cations. Additions to 2-indanones generally give dibenzoisochromenones by sequential…
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