Chemical communications (Cambridge, England)
Equilibrium molecular structure of cyclic(alkyl)(amino)carbene copper(I) carbazolide with intramolecular agostic and anagostic C-H⋯Cu interactions from gas-phase electron diffraction.
Alexander V Belyakov, Nadezhda S Kormil'tsyna, Ekaterina P Altova, Pavel Yu Sharanov, Igor F Shishkov, Alexander S Romanov
Published: 202510.1039/d5cc05082k
Abstract
The first gas-phase electron diffraction structure of a "carbene-metal-amide" (CMA) complex has been characterised. Strong agostic and weak anagostic C-H⋯Cu intramolecular interactions have been revealed and correlated with significant bending of the…
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