Chemical communications (Cambridge, England)
Catalytic dinitrogen silylation by tris(pyrazolyl)borate-supported titanium complexes.
Chenrui Liu, Ling-Ya Peng, Yumeng Chen, Jingyi An, Zhaoxin Li, Wenshuang Huang, Ganglong Cui, Shaowei Hu
Published: 202610.1039/d5cc04879f
Abstract
Titanium dinitrogen complexes supported by tris(pyrazolyl)borate and alkoxide/aryloxide ligands catalyse N2 silylation. Titanium silylimide and disilylamide model complexes represent the first well-defined group IV imide/amide catalysts for N2 reduct…
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