Chemical communications (Cambridge, England)
B2Pin2-enabled reductive thioesterification of aryl triflates with thiocarbonates.
Houguang Shi, Fan Wu, Wei Zhu, Hong C Shen, Shaojie Xu, Xiaotai Wang, Hegui Gong
Published: 202510.1039/d5cc04038h
Abstract
In this work, we demonstrate a B2Pin2-mediated reductive coupling of aryl triflates with thiocarbonates for aryl thioester synthesis. This method surpasses previous Zn-based protocols, especially for pyridyl and sterically hindered 2,6-disubstituted…
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