Journal of the American Chemical Society
Positional Isomerization of 1,2-Azaborine through BN-Benzvalene.
Tomoya Ozaki, Skylar Diamandis, Nina Rybansky, Xinyu Yang, Fan Bai, Bo Li, Jier Huang, Shih-Yuan Liu
Published: 202610.1021/jacs.5c21413
Abstract
A photochemical positional isomerization approach for converting readily accessible C5-aryl-1,2-azaborines into their C4-aryl counterparts via a BN-benzvalene intermediate is described. The oxidative radical cation pathway from BN-benzvalene to the C…
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