Journal of the American Chemical Society
Extending the Distance Range in Double Electron-Electron Resonance Measurements of Transition Metal Clusters.
Selena J Lockyer, Lubomir Loci, Adam Brookfield, Grigore A Timco, George F S Whitehead, Shanshan Wan, Alice M Bowen, Richard E P Winpenny, Eric J L McInnes
Published: 202610.1021/jacs.5c20715
Abstract
We report ligand manipulation of high-nuclearity, paramagnetic transition metal clusters based on heterometallic {Cr7Ni} rings to significantly prolong electron spin phase memory time constants. This enables the application of Double Electron-Electro…
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