A Rational Design of Chiral Iron(III) Complexes for Photocatalytic Asymmetric Radical Cation (4 + 2) Cycloadditions and the Total Synthesis of (+)-Heitziamide A.

This work describes the design of chiral iron(III) photoredox catalysis for asymmetric radical cation reactions. The newly developed catalysis successfully minimizes the use of chiral sources and exhibits high tunability, thereby enabling a highly en…

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