Additive-Controlled Regioswitching in Ni-Catalyzed Enantioselective Hydrophosphination of Unactivated Alkenes.

Transition metal-catalyzed asymmetric hydrophosphination of unsaturated bonds offers the most direct route to chiral organophosphorus compounds. However, unactivated double bonds remain a longstanding challenge in this field due to their inherent low…

Preview only. Read the full abstract at the source