Journal of the American Chemical Society
Catalytic Enantioselective Synthesis of Planar-Chiral Cyclophanes via a Chiral Octahedral Cobalt(III)-Templated C-H Macrocyclization.
Bing-Jie Wang, Tian-Yu Jiang, Yao-Le Jiang, Xu Wu, Qi-Jun Yao, Bing-Feng Shi
Published: 202510.1021/jacs.5c18900
Abstract
The catalytic enantioselective synthesis of planar-chiral cyclophanes is a formidable challenge due to the entropic and stereoelectronic constraints inherent in macrocyclization. Herein, we report a strategy that employs a cobalt(II) precatalyst with…
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