Journal of the American Chemical Society
Nitrile RC≡N Triple Bond Cleavage by a Dicopper Nitrite Complex with N2 Elimination and Formation of RCO2- Carboxylate Ligands.
Jose Martinez Fernandez, Ai Vy Nguyen, Mojgan Gharaee, Alireza Haji Seyed Javadi, Thomas R Cundari, T Don Tilley
Published: 202610.1021/jacs.5c18844
Abstract
This contribution showcases the complete scission of nitrile RC≡N bonds by [Cu2(μ-κ1:κ1-O2N)DPFN][NTf2] (1-NTf2; DPFN = 2,7-bis(fluoro-di(2-pyridyl)methyl)-1,8-naphthyridine, NTf2- = N(SO2CF3)2-), with dinitrogen elimination. These reactions produce…
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