Journal of the American Chemical Society
Size-Dependent Optical Band Gaps in Metal-Organic Framework Nanoparticles.
Faiqa Khaliq, Ryan A Beck, Erik Svensson Grape, Golnaz Navidi, Miles Griffith, Checkers R Marshall, Xiaosong Li, Carl K Brozek
Published: 202510.1021/jacs.5c18410
Abstract
Decades of research into size-dependent semiconductor optical gaps have focused on quantum confinement as the dominant mechanism. Emerging reports indicate that lattice strain─intentional or incidental─can impart optical shifts similar or greater in…
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