Journal of the American Chemical Society
Oxo Ligand Insertion into Fe-C Bonds as a Platform for Oxygen Atom Insertion Catalysis.
Bin Feng, Yicheng Ji, Nobuyuki Yamamoto, Maren Pink, Xinfeng Gao, Hao Tang, Jeremy M Smith
Published: 202610.1021/jacs.5c18265
Abstract
Herein, we report the reactions of the Fe(II) alkyl and aryl complexes (Ph2B(tBuIm)2Fe(tBuImH)R, R = CH2tBu and Mes) with N2O and N-oxides (Me3NO and C5H5NO), affording oxygen-inserted Fe(II) alkoxide and aryloxide complexes (Ph2B(tBuIm)2Fe(tBuImH)OR…
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