Journal of the American Chemical Society
Gold(III)-Substituted Carbenes.
Rui Wei, Shuo Li, Nina Albouy, Sonia Mallet-Ladeira, Karinne Miqueu, Didier Bourissou
Published: 202610.1021/jacs.5c17756
Abstract
The Au(III)-substituted diazo compounds (N^C^C)AuC(N2)R (R = Dmp = 2,6-dimesitylphenyl and SiMe3) 1 and 6 were synthesized by reacting the (N^C^C)AuCl precursor with the corresponding lithiated diazo compounds. Dinitrogen extrusion was then promoted…
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