Journal of the American Chemical Society
Kinetic Resolution for 1,4-Spin-Center Shift-Based Reduction of Azaarene-Functionalized Secondary and Tertiary Allylic Alcohols.
Xiangbin Bai, Jialu Yao, Mengbo Zhang, Qing Peng, Wenxian Li, Xiaowei Zhao, Yanli Yin, Zhiyong Jiang
Published: 202510.1021/jacs.5c15917
Abstract
The spin-center shift (SCS) represents a highly effective strategy in the field of photoredox catalysis for the generation of radical intermediates. Owing to intrinsic mechanistic constraints, the reaction pathway primarily entails a 1,2-radical tran…
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