Journal of the American Chemical Society
Kinetic, Spectroscopic, and Computational Investigation of Oxidative Aminative Alkene Cleavage Reveals an N-Iodonium-Iminoiodinane Pathway.
Florian Ruepp, Vasily Grebennikov, Mykola Avramenko, Marc-Olivier Ebert, Bill Morandi
Published: 202510.1021/jacs.5c14977
Abstract
The combination of hypervalent iodine(III) oxidants and ammonia sources has been applied in various oxidative aminative transformations of high synthetic value. Central to these reactions is the proposed in situ generation of a four-electron oxidizin…
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