Journal of the American Chemical Society
An Ultrafast Benchmark for Ring Opening Metathesis Polymerization Catalysts: A Ruthenium Phosphinimine System Approaching the Diffusion Rate Limit.
Jordan R Gipper, Dean Afsar, Carson Cole, Sayantani Saha, Ryan J Rafferty, Patricia R Calvo, Peter E Sues
Published: 202510.1021/jacs.5c14780
Abstract
A ruthenium phenylidene complex bearing a monodentate phosphinimine ligand (Ru1) was investigated as a ring-opening metathesis polymerization (ROMP) catalyst. Building on prior studies showing ultrafast initiation and a bimolecular mechanism of decom…
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