Journal of the American Chemical Society
General Photo-Driven Chemoselective and Rapid Hydropentafluorosulfanylation of Alkenes via an Orchestrated Radical Chain Process.
Yuan-Yang Jiang, Jiang-Shan Zhang, Donglei Sun, Gang Wu, Zhe-Chang Kuang, Ning Zhang, Xiang-Yu Shen, Xiao-Long Zhang, Jingwen Jiang, Hui-Yi Yang, Wei Zhang, Xiao-Song Xue, Shuo Guo
Published: 202510.1021/jacs.5c14406
Abstract
Although chain propagation strategies could accelerate molecular synthesis (e.g., Kharasch-type additions of fluorinated haloalkanes), controllable radical processes remain challenging. Herein, we develop a novel metal-free radical chain transformati…
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