Journal of the American Chemical Society
Side-On N2 Binding and Reduction by a Heterotetrametallic Zr2Co2 Cluster.
Adwitiya Singh, Curtis E Moore, Christine M Thomas
Published: 202510.1021/jacs.5c14342
Abstract
In multimetallic compounds, N2 typically bridges late transition metals in an end-on (η1:η1) fashion while early transition metals often bind N2 side-on (η2), with the latter resulting in more significant N-N bond elongation. Herein, N2 fixation is a…
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