Journal of the American Chemical Society
Ambimodal (2 + 1)/(4 + 1) Pseudopericyclic Transition States in Reactions between Dihalocarbenes and Olefins.
Tongkun Wang, Xiao-Song Xue
Published: 202610.1021/jacs.5c13906
Abstract
We report the first example of ambimodal (2 + 1)/(4 + 1) pseudopericyclic transition states (TSs) in reactions between dihalocarbenes and olefins. Quasi-classical molecular dynamics simulations of the model reaction between dibromocarbene and 1,2-bis…
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