Journal of the American Chemical Society
Hydride Transfer Reactivity of an Open-Shell [Fe3H]- Cluster.
Lisa N Awaitey, Iván E Arvizo, Shao-Liang Zheng, Theodore A Betley
Published: 202510.1021/jacs.5c13885
Abstract
We report herein the synthesis and reactivity of the high-spin iron-hydride cluster [K(C222)][(tbsL)Fe3(μ3-H)]. Direct hydride transfer reaction attempts led to cluster reduction to afford the anionic cluster [(tbsL)Fe3]-, whereas metathesis using ph…
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