Biocatalytic Stereodivergent Construction of Axially Chiral Tri- and Tetrasubstituted Allenols via Desymmetric Hydroxylation.

Axially chiral allenes serve as versatile building blocks in organic synthesis and are important motifs in natural products. While enantioselective syntheses of disubstituted allenes have been well-established, catalytic construction of trisubstitute…

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